[1]郭天昊,曲树璋,张韬毅,等.第三组分在单中心催化剂聚合体系中作用的研究进展[J].高分子通报,2022,(10):41-53.[doi:10.14028/j.cnki.1003-3726.2022.10.006]
 GUO Tian-hao,QU Shu-zhang,ZHANG Tao-yi,et al.Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System[J].POLYMER BULLETIN,2022,(10):41-53.[doi:10.14028/j.cnki.1003-3726.2022.10.006]
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第三组分在单中心催化剂聚合体系中作用的研究进展()
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《高分子通报》[ISSN:1003-3726/CN:11-2051/O6]

卷:
期数:
2022年10期
页码:
41-53
栏目:
出版日期:
2022-10-20

文章信息/Info

Title:
Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System
作者:
郭天昊1 曲树璋2 张韬毅1 王伟2
1. 中国石化北京化工研究院 材料科学研究所, 北京 100013;
2. 中国石化北京化工研究院 医用卫生材料研究所, 北京 100013
Author(s):
GUO Tian-hao1 QU Shu-zhang2 ZHANG Tao-yi1 WANG Wei2
1. Institute of Materials Science, Sinopec Beijing Research Institute of Chemical Industry, Beijing 100013, China;
2. Institute of Medical and Health Materials, Sinopec Beijing Research Institute of Chemical Industry, Beijing 100013, China
关键词:
单中心催化剂第三组分链转移配位链转移聚合链穿梭聚合
Keywords:
Single-site catalystThe third componentChain transferCoordination chain transfer polymerizationChain shuttle polymerization
DOI:
10.14028/j.cnki.1003-3726.2022.10.006
文献标志码:
A
摘要:
本文综述了烯烃聚合的单中心催化剂体系中第三组分的影响。作为活性中心形成的非必要组分,第三组分对聚合物结构及聚合行为有重要影响。本文涉及了烷基金属类第三组分对聚合物结构、组成、分子量以及聚合行为的影响,总结了第三组分对单一催化剂体系、复合催化剂体系以及单一单体和多种单体的聚合体系的影响,重点讨论了链转移机理、配位链转移聚合原理以及链穿梭聚合技术。
Abstract:
This article reviews the influence of the third component in the single-site catalyst system for olefin polymerization. As an unnecessary component for the formation of active centers, the third component has an important influence on the polymer structure and polymerization behavior. This article deals with the influence of the third component of metal alkyls on the structure, composition, molecular weight and polymerization behavior of the polymer, and summarizes the influence of the third component on the polymerization of a single catalyst system, a composite catalyst system, and a single monomer and multiple monomers. The chain transfer mechanism, coordination chain transfer polymerization principle and chain shuttle polymerization technology are presented.

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备注/Memo

备注/Memo:
收稿日期:2021-8-16;改回日期:2022-4-3。
作者简介:郭天昊(1995-),男,硕士生,主要研究方向是聚烯烃单中心催化剂
通讯作者:张韬毅,E-mail:zhangtaoy.bjhy@sicopec.com;王伟,E-mail:wangw.bjhy@sinopec.com.
更新日期/Last Update: 2022-09-20